科研成果
| 论文编号: | DOI: 10.1002/chem.200801479 |
| 第一作者所在部门: | 天然产物研究中心 |
| 论文题目: | A Highly Enantioselective Organocatalytic Method for Reduction of Aromatic N-Alkyl Ketimines |
| 作者: | 王超 |
| 全部作者: | Chao Wang,Xinjun Wu,Li Zhou,Jian Sun |
| 论文出处: | |
| 刊物名称: | CHEMISTRY-A EUROPEAN JOURNAL |
| 年: | 2008 |
| 卷: | 14 |
| 期: | 29 |
| 页: | 8789-8792 |
| 联系作者: | 孙健 |
| 收录类别: | |
| 影响因子: | 5.454 |
| 摘要 : | A first highly enantioselective catalytic method has been developed for the reduction of aromatic N-alkyl ketimines by trichlorosilane under mild conditions using the newly designed Lewis base organocatalyst 3 that incorporates C- and S-chirality (see scheme). Excellent enantioselectivities up to 99.6 % ee and high yields were obtained for a wide range of substrates. |
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